The combination of several tools allow the fabrication of interesting structures. Standard lithography is a soft process based on organic masks that can't hold high temperatures. Good thermocromic VO2 requires a high temperature treatment to complete its crystalization, therfore a after lithography thermal treatment is needed to get the desired materials. Substoichiometric film of VO1.7 were deposited using pulsed laser deposition. 250 mTorr of O2 in 450 C completes the transformation.
a) The RBS energy spectrum (Backscattering of 1.8 MeV He+ ions) shows the samples are free of impurities. b) A constant VO2 stoichiometry is obtained down to 8 nm mass thickness. Electron micrographs of c) 15 and d)100 nm mass thickness films of VO2 samples after oxidation where the initial smooth amorphous VO1.7 film is traded by a VO2 granular structure.