Rene Lopez
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Pulsed laser deposition and oxidation of vanadium into VO2

The combination of several tools allow the fabrication of interesting structures. Standard lithography is a soft process based on organic masks that can't hold high temperatures. Good thermocromic VO2 requires a high temperature treatment to complete its crystalization, therfore a after lithography thermal treatment is needed to get the desired materials. Substoichiometric film of VO1.7 were deposited using pulsed laser deposition. 250 mTorr of O2 in 450 C completes the transformation.

a) The RBS energy spectrum (Backscattering of 1.8 MeV He+ ions) shows the samples are free of impurities.  b) A constant VO2 stoichiometry is obtained down to 8 nm mass thickness. Electron micrographs of c) 15 and d)100 nm mass thickness films of VO2 samples after oxidation where the initial smooth amorphous VO1.7 film is traded by a VO2 granular structure.

In  this image the evolution of a thin film vs. annealing time in the above mentioned conditions. Reflections taken at 75 degrees and IR laser (980 nm).
Thinner films show similar behavior, but the reflection is changed by an scattering process since the films have broken into small particles
If the conditions are varied slightly, the oxidation of the vanadium proceed to higher oxides. In the figure, the pass into V2O5. Abruptly different in wetting properties as can be seen in the following figure.

 
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